No..... this might be true if you had spools in both axles. All 4 wheels ARE NOT locked together like you seem to think. your brake bias is still heavily toward the front. the braking power of the front brakes is not distributed through the drivelineThere's what brake pads are applying, and that doesn't change with switching to 4wd. But now the braking force is getting distributed to all 4 wheels in an even fashion, in the same way that acceleration is spread among all 4 wheels.
I hope I explained it better.